Gas-liquid reactions are very common in Chemical Process Industry and contribute to more than 30% of all the chemical commercial reactions. There are several commercially important reactions where the gas phase is pure/explosive/toxic.
In all these cases the gas phase is expensive and complete utilization of the solute gas is desired. The key feature of these reactors is the efficiency at which gas-liquid mixing occurs. For this purpose, it is important that the un-reacted gas from the gas space is drawn back into liquid. This difficult task has been achieved in the recently developed novel reactor design (which is patented). It uses the self induction principle for impellers. Energy efficient impeller designs have been developed for gas induction and gas dispersion. It is also efficient for gas-liquid-solid three phase reactions. The solid phase may be a catalyst or undergo a chemical reaction.
The solids concentration may vary from 0.005% v/v (in the case of noble metal catalyst) or 25% v/v (when solids undergo chemical reaction). It is a proven design and a large number of reactors are in successful commercial operation with a size range from 500 to 20,000 Liters.
Over One Hundred and Ten Reactors are in successful commercial operation. Following are some details:
No | Application | Range of reactor volume | Product category |
1. | Saturation of double bonds. For example, In this case paraffin’s are formed from olefins or saturated fatty acids or saturated oils from the corresponding unsaturated acids and oils. | 5 m3 - 20 m3 | Fatty acids, hydrogenation (or hardening) of natural oils. |
2. | Nit rile to amine. In this case C º N group is converted in to –CH2NH2. | 0.1 m3 - 8 m3 | Soap intermediates, Specialty chemicals |
3. | Saturation of aromatic ring. The ring of substituted aromatic compounds are saturated. | 0.5 m3 - 4.0 m3 | Substituted anthraquinones, specialty chemicals, perfumery chemicals, cyclohexyl amine |
4. | Hydrogenation of aromatic nitro-compounds such m-dinitrobenzene, o-nitroaniline, p-nitroaniline, o-dinitrobenzene, p-dinitrobenzene’s, nitrotoluenes, nitroxylenes, nitro chlorobenzenes, nitroanisoles, nitro cumenes, etc. | 2 m3 - 12 m3 | Dye, pharmaceutical and agro-chemical intermediates. |
5. | Reductive amination and reductive alkylation. | 1 m3 - 5 m3 | Surface active agents, Pharmaceutical intermediates. |
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8 | SR. | CLIENT | CAPACITY | DESIGN PRESSURE | DESIGN | M. O. C. | QUANTITY | INSPECTION | YEAR | SERVICE |
9 | NO. | LITRE/KL | Kg/cm� (g) | TEMP. �C | ||||||
10 | 1 | M/s. Emmellen Biotech Pharma ltd.Mahad | 500 | 10 | 100 | SS 316 | 1 | Internal | 1996 | Hydrogenation |
11 | 2 | M/s. Emmellen Biotech Pharma ltd.Mahad | 500 | 10 | 100 | SS 316 | 1 | Internal | 1997 | Hydrogenation |
12 | 3 | M/s. Jayant Oil Mill , Bhandup (Mumbai) | 2200 | 30 | 200 | SS 316 | 1 | Third Party | 1998 | Hydrogenation |
13 | 4 | M/s. Aarti Industries Ltd. Vapi Gujarat | 12000 | 44 | 200 | SA 516 Gr.70 | 2 | Third Party | 1998 | Amonolysis |
14 | 5 | M/s. Emmellen Biotech Pharma ltd.Mahad | 250 | 10 | 100 | SS 316 | 1 | Internal | 1998 | Hydrogenation |
15 | 6 | M/s. Catapharma Chem. Pvt. Ltd. Nashik | 3000 | 32.7 / F.V. | 150 | SS 304 | 1 | Third Party | 1999 | Hydrogenation |
16 | 7 | M/s. Galaxy Laboratories Pvt. Ltd Aurangabad | 1000 | 35.15 | 200 | SS 316 | 1 | Internal | 1999 | Hydrogenation |
17 | 8 | M/s. Emmellen Biotech Pharma ltd.Mahad | 250 | 10 | 100 | SS 316 | 1 | Internal | 1999 | Hydrogenation |
18 | 9 | M/s. Aarti Industries Ltd. Vapi Gujarat | 3000 | 37 | 200 | SS 316L | 1 | Third Party | 2000 | Hydrogenation |
19 | 10 | M/s. Alta Laboratories Ltd. | 100 | 50 | 200 | SS 316 | 1 | Internal | 2000 | Carboxylation |
20 | 11 | M/s. Erie Chem Pvt Ltd. | 100 | 20 | 150 | SS 316 | 1 | Internal | 2000 | Hydrogenation |
21 | 12 | M/s. Aarti Industries Ltd. Jghgadia Gujarat | 1000 | 37 | 150 | SS 316L | 1 | Third Party | 2000 | Hydrogenation |
22 | 13 | M/s. Erie Chem Pvt Ltd. | 5000 | 15 | 150 | SS 316 | 1 | Third Party | 2000 | Hydrogenation |
23 | 14 | M/s. Aarti Industries Ltd. Jhagadia Gujarat | 50 | 25 | 200 | SS 316 | 1 | Internal | 2001 | Hydrogenation (Pilot Plant) |
24 | 15 | M/s. Tagros Chemicals (I) Ltd. Chennai | 2000 | 10 | 150 | SS 316 | 1 | Dalal Mott McDonald | 2002 | Hydrogenation |
25 | 16 | M/s. Galaxy Laboratories Pvt. Ltd Aurangabad | 2000 | 25 | 150 | SS 316 | 1 | Internal | 2002 | Hydrogenation |
26 | 17 | M/s. Metropolitan Eximchem Ltd. | 200 | 70 | 200 | SS 316 | 1 | Internal | 2002 | Hydrogenation |
27 | 18 | M/s. Catapharma Chem. Pvt. Ltd. Nashik | 5000 | 28 | 200 | SS 316L | 1 | Third Party | 2002 | Hydrogenation |
28 | 19 | M/s. Aryan Pesticides Ltd. Roha (Div. Of Deepak Nitrite Ltd.) | 3500 | 12 | 200 | SS 316 | 2 | Internal | 2002 | Hydrogenation |
29 | 20 | M/s. Hindustan monomers Ltd. | 300 | 35 | 200 | SS 316 | 1 | Third Party | 2003 | Hydrogenation (Pilot Plant) |
30 | 21 | M/s. Catapro Technologies | 100 | 80 | 200 | SS 316 | 1 | Third Party | 2004 | Hydrogenation (Pilot Plant) |
31 | 22 | M/s. Catapharma Chem. Pvt. Ltd. | 5000 | 30 | 200 | SS 316 | 1 | Third Party | 2004 | Hydrogenation |
32 | 23 | M/s. MDB Chemicals Pvt Ltd. | 5000 | 30 | 200 | SS 316 | 1 | Third Party | 2004 | Hydrogenation |
33 | 24 | M/s. Aryan Pesticides Ltd. | 3000 | 20 | 150 | SS 316 | 1 | Internal / Client | 2004 | Hydrogenation |
34 | 25 | M/s.Ganesh Polychem ltd. | 3000 | 50 | 150 | SS 316 | 1 | Third Party | 2004 | Hydrogenation / Amination |
35 | 26 | M/s. Aarti Industries Ltd. | 10000 | 15 | 150 | SS 316 | 1 | Third Party | 2004 | Hydrogenation |
36 | 27 | M/s. Aarti Healthcare Ltd. Dombivli | 2200 | 15 | 200 | SS 316 | 2 | Third Party | 2004 | Hydrogenation |
37 | 28 | M/s. Aarti Healthcare Ltd. Dombivli | 1100 | 15 | 200 | SS 316 | 2 | Third Party | 2004 | Hydrogenation |
38 | 29 | M/s. Ven Petrochem Ankaleshwar | 600 | 25 | 150 | SS 316 | 1 | Internal | 2004 | Hydrogenation |
39 | 30 | M/s. Modepro India Pvt. Ltd. (Navi Mumbai) | 2000 | 20 | 150 | SS 316 | 1 | Internal | 2004 | Hydrogenation |
40 | 31 | M/s. Bharat Chemicals Ltd. Tarapur | 6000 | 22 | 150 | SS 316 | 1 | Third Party | 2005 | Hydrogenation |
41 | 32 | M/s. Aarti Industries Ltd. Vapi Gujarat | 7500 | 20 | 150 | SS 316 | 1 | Third Party | 2006 | Hydrogenation |
42 | 33 | M/s. Dheeraj Intermediates Ltd. Vapi | 10000 | 20 | 150 | SS 316 | 1 | Third Party | 2006 | Hydrogenation |
43 | 34 | M/s. Ganesh Polychem ltd. | 8000 | 50 | 250 | SA 515 Gr.70 | 1 | Third Party | 2006 | Hydrogenation |
44 | 35 | M/s. Aarti Industries Ltd. Tarapur | 6000 | 20 | 150 | SS 316 | 1 | Third Party | 2006 | Hydrogenation |
45 | 36 | M/s. Suven Life Sciences Pvt. Ltd. Hyderabad | 5000 | 35 | 200 | SS 316 | 1 | Internal | 2006 | Hydrogenation |
46 | 37 | M/s. Suven Life Sciences Pvt. Ltd. Hyderabad | 1000 | 35 | 200 | SS 316 | 1 | Internal | 2006 | Hydrogenation |
47 | 38 | M/s.Suven Life Sciences Pvt. Ltd. | 3000 | 35 | 200 | SS 316 | 1 | Internal | 2006 | Hydrogenation |
48 | 39 | M/s. United Phosphorus Ltd. Jhagadia | 7000 | 25 | 150 | SS 316 | 1 | Internal | 2006 | Hydrogenation |
49 | 40 | M/s. Indo Amines | 2500 | 10 | 100 | SS 316 | 1 | Internal | 2007 | Hydrogenation |
50 | 41 | M/s. Karnataka Malladi Biotech Ltd. Mahad | 1000 | 15 | 150 | SS 316 | 2 | Internal | 2008 | Hydrogenation |
51 | 42 | M/s. Indo Amines | 2000 | 15 | 150 | SS 316 | 1 | Internal | 2008 | Hydrogenation |
52 | 43 | M/s. Alta Laboratories Ltd. | 4500 | 18 | 250 | SA 515 Gr.70 | 1 | Internal | 2008 | Carbonation |
53 | 44 | M/s. Chemie Organic Industries. | 4000 | 15 | 150 | SS 316 | 1 | Internal | 2009 | Hydrogenation |
54 | 45 | M/s. GalaxyLaboratories Pvt. Ltd. | 3000 | 35 | 150 | SS 316 | 1 | Internal | 2009 | Hydrogenation |
55 | 46 | M/s. Vichow Labs | 1200 | 35 | 150 | SS 316 | 1 | Internal | 2009 | Hydrogenation |
56 | 47 | M/s. Richter Themis Medicare Pvt Ltd. | 2500 | 15 | 150 | SS 316 | 1 | Internal | 2009 | Hydrogenation |
57 | 48 | M/s. Deepak Nitrite Ltd. | 5400 | 21 | 150 | SS 316 | 1 | Third Party | 2009 | Hydrogenation |
58 | 49 | M/s. Alphs Chemicals. | 30 | 10 | 100 | SS 316 | 1 | Internal | 2010 | Pilot Plant |
59 | 50 | M/s. Emmellen Biotech Pharma ltd. (Embio) | 1000 | 10 | 100 | SS 316 | 1 | Internal | 2011 | Hydrogenation |
60 | 51 | M/s. Kusa Chemicals Pvt. Ltd. | 5000 | 10 | 100 | SS 316 | 1 | Internal | 2011 | Hydrogenation / Ethoxylation |
61 | 52 | M/s. Chemie Organic Industries. | 10000 | 24 | 200 | SS 316L | 1 | Internal | 2012 | Hydrogenation |
62 | 53 | M/s. Gujarat Organics Ltd. | 10000 | 15 | 250 | SS 316 | 1 | Internal | 2012 | Carboxylation |
63 | 54 | M/s. Aarti Industries Ltd. | 7500 | 25 | 200 | SS 316 | 1 | Third Party | 2012 | Hydrogenation |
64 | 55 | M/s. Cosmo Chemical | 6000 | 20 | 250 | SS 316 | 1 | Internal | 2012 | Hydrogenation |
65 | 56 | M/s. Ecologic Chemicals | 6000 | 22 | 200 | SS 316 | 1 | Third Party | 2012 | Hydrogenation |
66 | 57 | M/s. Avra Laboratories Ltd. | 2500 | 12 | 150 | SS 316 | 1 | Internal | 2012 | Hydrogenation |
67 | 58 | M/s. Somu Organochem Ltd. | 3600 | 32 | 250 | SS 316 | 1 | Internal | 2012 | Hydrogenation |
68 | 59 | M/s. Kalpasutra Chemicals | 5000 | 35 | 260 | SS 316 | 1 | Internal | 2013 | Hydrogenation |
69 | 60 | M/s. Aarti Industries Ltd. | 9000 | 22 | 150 | SS 316 | 1 | Third Party | 2015 | Hydrogenation |
70 | 61 | M/s. Deepak Nitrite Ltd. | 4000 | 25 | 150 | SS 316 | 2 | Third Party | 2015 | Hydrogenation |
71 | 62 | M/s. Deepak Nitrite Ltd. | 6000 | 25 | 150 | SS 316 | 2 | Third Party | 2015 | Hydrogenation |
72 | 63 | M/s. Glochem Lab | 1000 | 3 | SS 316 | 1 | ||||
73 | 64 | M/s. Aarti Industries Ltd. (Clad Steel) | 12000 | 75 | 200 | SA 515 Gr.70 + SS 316L | 1 | Third Party | 2015 | Hydrogenation |
74 | 65 | M/s. Aarti Industies Ltd. | 20000 | 90 | 300 | SA 515 Gr.70 + SS 316L | 1 | Third Party | 2015 | Ethylation |
75 | 66 | M/s. Hikal Ltd. | 4000 | 25 | 150 | SS 316 | 1 | Third Party | 2015 | Hydrogenation |
76 | 67 | M/s. Kalpasutra Chemicals | 15200 | 35 | 250 | SS 316 | 1 | Third Party | 2016 | Hydrogenation |
77 | 68 | M/s. United Phosphorus Ltd. | 15000 | 25 | 150 | SS 316 | 1 | Third Party | 2016 | Hydrogenation |
78 | 69 | M/s. Hikal Ltd. | 4000 | 25 | 150 | SS 316 | 1 | Third Party | 2016 | Hydrogenation |
79 | 70 | M/s. IOL Chemicals & Pharma. | 3000 | 15 | 150 | SS 316 | 1 | Client | 2016 | Hydrogenation |
80 | 71 | M/s. Galaxy Laboratories Pvt. Ltd. | 4000 | 35 | 150 | SS 316 | 3 | Client | 2017 | Hydrogenation |
81 | 72 | M/s. Chemie Organic Chemical | 5000 | 37 | 150 | SS 316 | 1 | Client | 2017 | Hydrogenation |
82 | 73 | M/s. Aarti Industries Ltd. (Apple Div.) | 250 | 80 | 300 | SS 316 | 1 | Third Party | 2018 | Multiple Service Pilot Reactor |
83 | 74 | M/s. Chemie Organic Chemical | 4500 | 20 | 200 | SS 316 | 1 | Client | 2017 | Hydrogenation |
84 | 75 | M/s. Jayant Agro-Organics Ltd. | 3500 | 45 | 300 | SS 316 | 1 | Third Party | 2018 | Hydrogenation |
85 | 76 | M/s. Aarti Industries Ltd. (Alchemie) | 3500 | 20 | 200 | SS 317 | 1 | Third Party | 2018 | Hydrogenation |
86 | 77 | M/s. Galaxy Laboratories Pvt. Ltd. | 8000 | 35 | 200 | SS 316 | 1 | Client | 2018 | Hydrogenation |
87 | 78 | M/s. Privi Organics (I) Ltd. | 12000 | 22 | 200 | SS 316 | 1 | Client | 2018 | Hydrogenation |
88 | 79 | M/s. Privi Organics (I) Ltd. | 8000 | 22 | 200 | SS 316 | 2 | Client | 2019 | Hydrogenation |
89 | 80 | M/s.R. N. Laboratories | 4500 | 20 | 150 | SS 316 | 1 | Client | 2019 | Hydrogenation |
90 | 81 | M/s.Chemie Organic Chemicals (I) Pvt. Ltd. | 4500 | 20 | 150 | SS 316 | 1 | Client | 2019 | Hydrogenation |
91 | 82 | M/s.Galaxy Laboratories Pvt. Ltd. | 4000 | 35 | 150 | SS 316 | 1 | Client | 2019 | Hydrogenation |
92 | 83 | M/s.Deepak Nitrite Ltd. | 8000 | 25 | 200 | SS 316 | 2 | Client | 2019 | Hydrogenation |
93 | 84 | M/s.Alkyl Amine Chemicals Pvt. Ltd. | 4625 | 5 | 200 | SS 316 | 2 | Client | 2019 | Hydrogenation |
94 | 85 | M/s.Merck Performance Chemicals Pvt. Ltd. | 1000 | 10 | 200 | SS 316 | 1 | Client | 2019 | - |
95 | 86 | M/s.Omkar Laboratories Pvt. Ltd. | 250 L-W.V./420 L-G.V. | 35 | 200 | SS 316 | 1 | Client | 2019 | Hydrogenation |
96 | 87 | M/s.Alkyl Amine Chemicals Pvt. Ltd. | 7175 | F.V. / 10 | 300 | SS 316L | 1 | Client | 2020 | Hydrogenation |
97 | 88 | M/s. Alkyl Amines Chemicals Ltd. | 7175 | F.V. / 30 | 300 | SS 316L | 1 | Client | 2020 | Hydrogenation |
98 | 89 | M/s. Anupam Rasayan | 8.1 KL-W.V/13.4 KL-G.V. | F.V. / 32.5 | 175 | SS 316 | 2 | Client | Under Execution | Hydrogenation |
99 | 90 | M/s. Ketul Chem | 6.2 KL-W.V./10.3 KL-G.V. | F.V. / 15 | 200 | SS 316 / Dual Cert. SS 316L | 1 | Client | 2020 | Hydrogenation |
100 | 91 | M/s. Privi Organics (I) Ltd. | 8 KL-W.V./13.66 KL-G.V. | 45 | 230 | SS 316 | 1 | Client | 2020 | Hydrogenation |
101 | 92 | M/s. Ketul Chem | 3 KL-W.V./4.6 KL-G.V. | F.V. / 15 | 200 | SS 316 / Dual Cert. SS 316L | 1 | Client | 2020 | Hydrogenation |
102 | 93 | M/s. Chemieorganic Chemicals(I) Pvt. Ltd. | 4.5 KL-W.V./7.2 KL-G.V. | 20 | 150 | SS 316 / Dual Cert. SS 316L | 1 | Client | 2020 | Hydrogenation |
103 | 94 | M/s. Alkyl Amines Chemicals Ltd. | 4.56 KL-G.V. | 45 | 300 | SS 316 / Dual Cert. SS 316L | 1 | Client | 2020 | Hydrogenation |
104 | 95 | M/s. Omkar Lab (Vasai) | 1 KL-W.V. / 1.76 KL-G.V. | 25 | 200 | SS 316 | 1 | Client | Under Execution | Hydrogenation |
105 | 96 | M/s. Omkar Lab (Vasai) | 3 KL-W.V. / 5 KL-G.V. | 25 | 200 | SS 316 | 1 | Client | Under Execution | Hydrogenation |
106 | 97 | M/s. Chemieorganic Chemicals(I) Pvt. Ltd. | 10 KL-W.V. / 14.5 KL-G.V. | 24 | 150 | SS 316 | 1 | Client | Under Execution | Hydrogenation |
107 | 98 | M/s. Embio Ltd. | 1 KL-W.V. / 1.57 KL-G.V. | 15 | 150 | SS 316 | 1 | Client | Under Execution | Hydrogenation |
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